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Article:Synthesis, Spectral and Thermal Properties of Bis Thiourea Zinc Acetate (BTZA) nonlinear Optical Single Crystal

by Dr. J. Thomas Joseph Prakash, L. Ruby Nirmala
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International Journal of Computer Applications
Foundation of Computer Science (FCS), NY, USA
Volume 8 - Number 2
Year of Publication: 2010
Authors: Dr. J. Thomas Joseph Prakash, L. Ruby Nirmala
10.5120/1188-1660

Dr. J. Thomas Joseph Prakash, L. Ruby Nirmala . Article:Synthesis, Spectral and Thermal Properties of Bis Thiourea Zinc Acetate (BTZA) nonlinear Optical Single Crystal. International Journal of Computer Applications. 8, 2 ( October 2010), 7-11. DOI=10.5120/1188-1660

@article{ 10.5120/1188-1660,
author = { Dr. J. Thomas Joseph Prakash, L. Ruby Nirmala },
title = { Article:Synthesis, Spectral and Thermal Properties of Bis Thiourea Zinc Acetate (BTZA) nonlinear Optical Single Crystal },
journal = { International Journal of Computer Applications },
issue_date = { October 2010 },
volume = { 8 },
number = { 2 },
month = { October },
year = { 2010 },
issn = { 0975-8887 },
pages = { 7-11 },
numpages = {9},
url = { https://ijcaonline.org/archives/volume8/number2/1188-1660/ },
doi = { 10.5120/1188-1660 },
publisher = {Foundation of Computer Science (FCS), NY, USA},
address = {New York, USA}
}
%0 Journal Article
%1 2024-02-06T19:56:29.331262+05:30
%A Dr. J. Thomas Joseph Prakash
%A L. Ruby Nirmala
%T Article:Synthesis, Spectral and Thermal Properties of Bis Thiourea Zinc Acetate (BTZA) nonlinear Optical Single Crystal
%J International Journal of Computer Applications
%@ 0975-8887
%V 8
%N 2
%P 7-11
%D 2010
%I Foundation of Computer Science (FCS), NY, USA
Abstract

Bisthiourea Zinc Acetate (BTZA) a new semi organic nonlinear optical material has been synthesized by slow evaporation method using water as a solvent. The solubility studies have been carried out in aqueous solution in the temperature range 25 ˚C – 45 ˚C. Crystals have been grown from low temperature solution method by slow evaporation of saturated aqueous solution at room temperature. Single Crystal X-ray diffraction study has been carried out to determine the lattice parameter of the grown crystal. The spectral bands have been compared with similar thiourea complexes using FTIR spectrum in the range 400 – 4000 cm-1. Optical transmittance and absorption percentage of the grown crystal have been measured from UV-Vis studies. The Second harmonic generation test of BTZA has revealed the nonlinear nature of the crystal. The thermal behavior has been investigated by thermogravimetric (TGA) and Differential Thermogram analyses (DTA). The mechanical strength and work hardening coefficient of the grown crystal have been analyzed by Vicker’s microhardness method.

References
  1. Andreeti G.D, Cavalca L, Musatti A, Acta Crystallogr. B24 (1968)683.
  2. Anie Roshan S, Joseph C, Ittachen M.A., Mater.Lett.49 (2001)299.
  3. Bairava Ganesh R, Kannan V, Sathyalakshmi R, Ramasamy P. Mater. Lett. 61(2007) 706.
  4. Bhat H.L, Prog. Crystal Growth and Charact. 11 (1985) 57.
  5. Christian R, Solvents and Solvents Effects Inorganic chemistry, VCH, NewYork, 1990.
  6. Hanneman M, Metall, Manch. 23 (1941) 135.
  7. Hellwege K.H, Hellwege A.M, Landolt-Bornstein, Group II 14 (1982)584.
  8. Iwai M, Kobayashi T, Furya H, Mori Y, Sasaki T, Jpn.J.Appl.Phys. 36(1997)1.276.
  9. Janos Madarasz, Petra Bombicz, Masayuki Okuya, Shoji Kaneko, Solid State Ionics 439 (2001)41.
  10. Jayalakshmi D, Kumar J, Cryst.Res.Technol.41 (2006)37.
  11. Jayalakshmi D, Sankar R, Jayavel R, Kumar J, J.Cryst.Growth 276(2005)243-246.
  12. Kannan V, Rajesh N.P, Bairava Ganesh R, Ramasamy P, J.Cryst.Growth 269(2004)565.
  13. Krishnan Rao K, Surender V,Bull. Mater.Sci. 24 (2001) 665.
  14. Kurtz S.K, Perry T.T.. J. Appl. Phys. 39 (1968) 3798.
  15. Ledoux L synth.Metal 54(1993)123.
  16. Luigi Cavalca, Giovanna Fava Gasparri, Giovanni Dario Andreetti, Paolo Domiano Acta Cryst.22 (1967)90.
  17. Lydia Caroline M, Vasudevan S, Current applied physics 9(2009)1054.
  18. Marey H.O, Warren L.F, Webb M.S, Ebbers C.A, Velsko S.P, Kennedy G.C, Catella G.C, Applied Opts.31 (1992)5051.
  19. Meera K, Muralidharan R, Dhanasekaran R, PrapunManyum, Ramasamy P, J.Cryst.Growth 263(2004)510.
  20. Meng F.., Lu M.K, Yang, Zeng H., Mater. Lett. 33(1998) 265.
  21. Mercy H.O, Rosker M.J, Warren L.F, Cunningham P.H, Thomas C.A, Deloach L.A, Velsko S.P, Ebbers C.A, Liao J.H, Kanatzidis M.G, Opt.Lett.20 (1995) 252.
  22. Meyers M.A, some aspects of the hardness of metals, Ph.D., Thesis, Dreft, (1951)
  23. Mohankumar R, Rajan Babu D, Ravi G, Jayavel R, J.Cryst.Growth 250(2003)113.
  24. Mott B.W, Micro indentation Hardness Testing, Butterworth London (1956)
  25. Nakamoto K, IR Spectra of Inorganic and Co-ordination Compounds. IIEd, Wiley, New York, 1978.
  26. Onitsch E.M, Mikroscopia 2 (1947) 131
  27. Pracilla Jeyakumari A, Ramajothi J, Dhanuskodi S, J.Cryst.Growth 269(2004)558.
  28. Prasad P.N and Williams D.J, Introduction to Nonlinear Optical Effects in Molecules and polymers Wiley Interscience, New York, 1991.
  29. Raja Sekaran R, Ushasree P.M, Jayavel R, Ramasamy P, J.Cryst.Growth 229(2001)563.
  30. Ramajothi J, Dhanuskodi S, Nagarajan K, Cryst. Res. Technol. 39(2004)414.
  31. Senthil Pandian M, BalaMurugan N, Bhagavannarayana G, Ramasamy P, J.Crys.Growth 10 (2008) 4143-4147.
  32. Sun H.Q, Yuan D.R, Wang X.Q, Cheng X.F, Gong C.R, Zhou M, Xu H.Y, Wei X.C, Luan C.N, Pan D.Y, Li Z.F, Shi X.Z, Cryst.Res.Technol.40 (2005)882.
  33. Swaminathan K, Irving H.M.N.H, Inorg J, Nucl. Chem. 26(1964)1291
  34. Ushasree P.M, Jayavel R, Ramasamy P, Mater. Sci. Eng. B65 (1999)153.
  35. Ushasree P.M, Jayavel R, Subramanian C, Ramasamy P, Bull.Electorchem.14 (1998)407.
  36. Ushasree P.M, Muralidharan R, Jayavel R, Ramasamy P, J.Cryst.Growth 218(2000)365.
  37. Wang X.Q, Xu D, Yuan D.R, Tian Y.P, Yu W.T, Sun S.Y, Yang Z.H, Fang Q, Lu M.K, Yan Y.X, Meng F.Q, Guo S.Y, Zhang G.H, Jiang M.H, Mater.Res.Bull.34 (199) (2003).
  38. Yuan D.R, Xu D, Zhang N, Liu M.G, Jiang.Chin M.H, Phys.Lett.13 (1996)841.
Index Terms

Computer Science
Information Sciences

Keywords

Non linear optical material Growth from solutions X-ray diffraction FT-IR Optical transmission Second harmonic generation TGA/DTA

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